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4.5 Acids, alkalis and the pH scale

What makes a solution acidic or alkaline, the pH scale from 0 to 14, measuring pH with universal indicator or a pH probe, and the colours of common indicators.

AQA Edexcel OCR 1 min read

Acids and alkalis

Key terms

  • Acid: a substance that produces hydrogen ions, \mathrm{H^+}, when dissolved in water.
  • Base: a substance that neutralises an acid, such as a metal oxide, hydroxide or carbonate.
  • Alkali: a base that dissolves in water. Alkalis produce hydroxide ions, \mathrm{OH^-}, in solution.

Common acids: hydrochloric acid (HCl), sulfuric acid (H2SO4), nitric acid (HNO3). Common alkalis: sodium hydroxide (NaOH), potassium hydroxide (KOH), calcium hydroxide (Ca(OH)2), ammonia solution.

The pH scale

The pH scale from 0 to 14 in universal indicator colours, with examples from stomach acid to oven cleaner, acids below 7, neutral at 7 and alkalis above 7
The pH scale from 0 to 14 in universal indicator colours, with examples from stomach acid to oven cleaner, acids below 7, neutral at 7 and alkalis above 7
  • pH below 7: acidic. The lower the pH, the more acidic (more \mathrm{H^+} ions).
  • pH 7: neutral, such as pure water.
  • pH above 7: alkaline. The higher the pH, the more alkaline (more \mathrm{OH^-} ions).

Measuring pH

  • Universal indicator (paper or solution): compare the colour with a chart. Quick, but only gives an approximate whole-number pH, and depends on judging a colour.
  • pH probe and meter: gives an accurate reading, often to one or two decimal places.

Other indicators

Single indicators only show whether a solution is acidic or alkaline, by a sudden colour change.

Indicator colours
IndicatorIn acidIn alkali
Litmusredblue
Methyl orangeredyellow
Phenolphthaleincolourlesspink

Methyl orange and phenolphthalein are used in titrations, because they change colour sharply.

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