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Physics · Particle model of matter

Internal energy

Explain that internal energy is the total kinetic and potential energy of the particles, and describe how heating changes it, using \(\Delta E = mc\Delta\theta\) for temperature changes.

  • 6 key terms
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Warm-up

Answer each one, then check.

  1. 1

    What is kinetic energy?

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    Energy stored in moving objects

  2. 2

    What is the equation for a change in thermal energy?

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    \(\Delta E = mc\Delta\theta\)

  3. 3

    What is temperature a measure of?

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    How hot something is

  4. 4

    What is a system?

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    An object or group of objects

  5. 5

    What is potential energy?

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    Stored energy due to position or bonds

Learning Objectives

  1. 1Define internal energy.
  2. 2Explain how heating changes the energy stored within a system.
  3. 3Use \(\Delta E = mc\Delta\theta\) to calculate the energy for a temperature change.
  4. 4Distinguish temperature from internal energy.

INTERNAL ENERGY

Internal energy is the total kinetic energy and potential energy of all the particles that make up a system.

Heating increases the energy of the particles. This either raises the temperature of the system or produces a change of state.

Temperature or Change of State?

Temperature rises

  • The kinetic energy of the particles increases.
  • The average speed of the particles increases.
  • Calculate with \(\Delta E = mc\Delta\theta\).

State changes

  • The potential energy of the particles increases.
  • The particles move further apart or become free.
  • The temperature stays the same.

Energy for a Temperature Rise

Calculate the energy needed to raise the temperature of 0.50 kg of water from 20 °C to 60 °C. c = 4200 J/kg °C.

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  1. 1 Temperature change \(60 - 20 = 40\) °C
  2. 2 Substitute \(\Delta E = 0.50 \times 4200 \times 40\)
  3. 3 Answer \(\Delta E = 84\,000\) J

Answer84 000 J (84 kJ)

Comparing Internal Energy

Which has more internal energy: 1.0 kg of water at 50 °C or 2.0 kg of water at 50 °C?

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  1. 1 Same temperature The particles have the same average kinetic energy
  2. 2 Different mass 2.0 kg has twice as many particles, so twice as much total energy

Answer2.0 kg of water has more internal energy.

Key Ideas

Learn the links.

  • Temperature

    Related to the average kinetic energy of the particles.

  • Internal energy

    The total, including potential energy.

  • Heating

    Increases internal energy by raising temperature or changing state.

  • Cooling

    Decreases internal energy.

More Energy

Explain what happens to the internal energy and the temperature of a beaker of water as it is heated (a) from 20 °C to 60 °C (b) while ice at 0 °C is melting.

1. Say what changes in the particles.

2. Say what happens to temperature.

A good answer shows: (a) Internal energy increases, mainly kinetic energy, so the temperature rises. (b) Internal energy increases as potential energy rises, but the temperature stays at 0 °C.

Can I...?

  1. 1Define internal energy.
  2. 2Say heating increases internal energy.
  3. 3Link kinetic energy to temperature.
  4. 4Link potential energy to change of state.
  5. 5Use \(\Delta E = mc\Delta\theta\).
  6. 6Compare two objects.
  7. 7Explain cooling.
  8. 8Use correct units.

Summary & Exam Focus

  • Internal energy = total kinetic + potential energy of the particles.
  • Heating raises temperature or changes state.
  • Temperature relates to kinetic energy.
  • \(\Delta E = mc\Delta\theta\).

Exam focus

What is meant by the internal energy of a system? (2 marks) (2 marks)

The total kinetic and potential energy of all the particles.

Key terms

The vocabulary this lesson expects you to use. Each one is linked from the first place it appears above.

Internal energy
The total kinetic and potential energy of all the particles in a system.
Kinetic energy
Energy of movement.
Potential energy
Energy stored because of forces between particles.
Specific heat capacity
Energy needed to raise 1 kg by 1 °C.
Temperature
A measure of the average kinetic energy of particles.
System
An object or group of objects.

Practice questions

Have a go at each one before you open its answer.

  1. Question 1 State 2 marks

    What is meant by the internal energy of a system?

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    Model answer

    The total kinetic energy and potential energy of all the particles that make up the system.

    Mark scheme

    • Total of kinetic energy — 1 mark
    • and potential energy of all the particles — 1 mark
  2. Question 2 Explain 3 marks

    A beaker of water is heated. Explain what happens to the energy stored within the water and to its temperature.

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    Model answer

    Heating increases the energy of the particles, so the internal energy increases. The kinetic energy of the particles increases, so the temperature rises.

    Mark scheme

    • Internal energy increases — 1 mark
    • Particles gain kinetic energy — 1 mark
    • Temperature rises — 1 mark
  3. Question 3 Calculate 3 marks

    Calculate the energy needed to raise the temperature of 0.50 kg of water from 20 °C to 60 °C. Specific heat capacity of water = 4200 J/kg °C.

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    Model answer

    \(0.50 \times 4200 \times 40 = 84\,000\) J

    Mark scheme

    • Temperature change 40 °C — 1 mark
    • Correct substitution — 1 mark
    • 84 000 J — 1 mark
  4. Question 4 Explain 2 marks

    1.0 kg of water and 2.0 kg of water are both at 50 °C. Which has more internal energy? Explain your answer.

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    Model answer

    2.0 kg, because it has twice as many particles at the same average kinetic energy, so its total energy is greater.

    Mark scheme

    • 2.0 kg of water — 1 mark
    • More particles so more total energy — 1 mark
  5. Question 5 Explain 4 marks

    Ice at 0 °C is heated and melts to water at 0 °C. Explain what happens to the internal energy and to the temperature during melting.

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    Model answer

    The internal energy increases because energy is supplied. The energy increases the potential energy of the particles as bonds are weakened, but does not increase their average kinetic energy, so the temperature stays the same.

    Mark scheme

    • Internal energy increases — 1 mark
    • Potential energy of particles increases — 1 mark
    • Kinetic energy does not increase — 1 mark
    • Temperature stays constant — 1 mark

Quick check

  1. Internal energy is the total of...

    1. Akinetic energy only
    2. Bthe temperature
    3. Cthe mass
    4. Dkinetic and potential energy of the particles
    Show answerHide answer

    D: kinetic and potential energy of the particles

    It includes both.

  2. Heating a substance...

    1. Aincreases its internal energy
    2. Bdecreases it
    3. Cdoes not change it
    4. Dremoves particles
    Show answerHide answer

    A: increases its internal energy

    Energy is transferred to the particles.

  3. Temperature is related to the particles'...

    1. Apotential energy
    2. Baverage kinetic energy
    3. Ccolour
    4. Dnumber
    Show answerHide answer

    B: average kinetic energy

    Faster particles mean a higher temperature.

  4. During melting the temperature...

    1. Arises quickly
    2. Bfalls
    3. Cstays constant
    4. Ddoubles
    Show answerHide answer

    C: stays constant

    The energy goes into potential energy.

  5. Which has more internal energy: 1 kg or 2 kg of water at the same temperature?

    1. A1 kg
    2. BThey are equal
    3. CCannot tell
    4. D2 kg
    Show answerHide answer

    D: 2 kg

    There are more particles.

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