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Physics · Particle model of matter
Particle motion and pressure in gases
Explain gas pressure using the particle model, describe how temperature and volume affect pressure, and use \(pV = \text{constant}\).
Warm-up
Answer each one, then check.
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1
What is pressure?
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Force per unit area
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2
What is the unit of pressure?
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Pascal (Pa)
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3
How do gas particles move?
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Randomly and quickly
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4
Convert 100 kPa to Pa.
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100 000 Pa
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5
Write 3 × 4 = ?
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12
Learning Objectives
- 1Explain how the motion of gas molecules is related to temperature and pressure.
- 2Explain qualitatively the relation between temperature and pressure of a gas at constant volume.
- 3Explain how changing the volume of a gas at constant temperature changes its pressure.
- 4Use \(pV = \text{constant}\).
GAS PRESSURE
Gas molecules are in constant random motion. Their collisions with the container walls cause the pressure, which acts at right angles to the wall.
For a fixed mass of gas at constant temperature, \(pressure \times volume = constant\), \(pV = \text{constant}\). It is given on the equation sheet.
Gas in a Container
Smaller volume means more frequent collisions.
Explaining Pressure
Use this chain of reasoning.
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1
Particles move randomly
They collide with the walls of the container.
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2
Each collision exerts a tiny force
At right angles to the wall.
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3
Many collisions
Together they give a steady force on the wall, and pressure = force ÷ area.
What Affects Gas Pressure
Learn the explanation for each.
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Temperature up (constant volume)
Effect on pressure: Increases. Explanation: Particles move faster, so collide harder and more often.
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Volume down (constant temperature)
Effect on pressure: Increases. Explanation: Particles are closer together so collide more often with the walls.
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Volume up (constant temperature)
Effect on pressure: Decreases. Explanation: Particles collide less often with the walls.
Using pV = constant
A gas at 100 000 Pa occupies 0.30 m³. It is compressed to 0.10 m³ at constant temperature. Calculate the new pressure.
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- 1 Write the relationship \(p_1V_1 = p_2V_2\)
- 2 Substitute \(100\,000 \times 0.30 = p_2 \times 0.10\)
- 3 Rearrange \(p_2 = \dfrac{30\,000}{0.10}\)
- 4 Answer \(p_2 = 300\,000\) Pa
Answer300 000 Pa
Heating at Constant Volume
Explain why the pressure in a sealed can increases when it is heated.
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- 1 Temperature rises The average kinetic energy of the molecules increases
- 2 Faster molecules They hit the walls harder and more often
- 3 Result The force on the walls, and so the pressure, increases
AnswerPressure increases because the faster molecules collide with the walls more often and with greater force.
Common Mistakes
Avoid these.
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Molecules expand
The molecules do not get bigger: they move faster.
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Collisions
Say 'more frequent and harder', not just 'more collisions'.
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Units
Pressure in pascals (Pa) and volume in m³.
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Constant
pV = constant only for a fixed mass at constant temperature.
Squash the Gas
A syringe holds 60 cm³ of air at 100 kPa. The plunger is pushed until the volume is 20 cm³ at constant temperature. Predict and calculate the new pressure.
1. Use p₁V₁ = p₂V₂.
2. Explain with particles.
A good answer shows: The pressure increases (particles hit the walls more often). p₂ = 100 × 60 ÷ 20 = 300 kPa.
Can I...?
- 1Explain gas pressure with particles.
- 2Say the force is at right angles to the wall.
- 3Explain the effect of temperature.
- 4Explain the effect of volume.
- 5Use \(pV = \text{constant}\).
- 6Give units of pressure.
- 7Compress and expand gases.
- 8Give clear explanations.
Summary & Exam Focus
- Gas pressure is caused by collisions with the walls.
- Higher temperature: faster molecules, more force, more often.
- Smaller volume at constant temperature: higher pressure.
- \(pV = \text{constant}\).
Exam focus
Explain, in terms of particles, why the pressure of a gas in a sealed container increases when the gas is heated. (3 marks) (3 marks)
Say faster molecules hit the walls more often and harder.
Key terms
The vocabulary this lesson expects you to use. Each one is linked from the first place it appears above.
- Pressure
- Force per unit area.
- Pascal
- The unit of pressure; one newton per square metre.
- Random motion
- Movement in any direction with no pattern.
- Fixed mass
- A sealed amount of gas with no particles added or removed.
- Compress
- Squash into a smaller volume.
- Kinetic energy
- Energy of movement.
Practice questions
Have a go at each one before you open its answer.
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Question 1 Explain 3 marks
A sealed container of gas is heated and the volume is constant. Explain, in terms of the particles, why the pressure of the gas increases.
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Model answer
The particles gain kinetic energy and move faster. They collide with the walls more often and with greater force, so the force on the walls per unit area increases.
Mark scheme
- Particles move faster or gain kinetic energy — 1 mark
- Collide with walls more often or harder — 1 mark
- So pressure increases — 1 mark
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Question 2 Explain 3 marks
The volume of a gas in a syringe is reduced. The temperature is constant. Explain, in terms of the particles, why the pressure increases.
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Model answer
The particles are closer together, so they collide with the walls more often. The force per unit area increases, so the pressure increases.
Mark scheme
- Volume decreases so the particles are closer — 1 mark
- More frequent collisions with the walls — 1 mark
- Pressure increases — 1 mark
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Question 3 Calculate 3 marks
A fixed mass of gas has a pressure of 100 000 Pa and a volume of 0.30 m³. The gas is compressed at constant temperature to a volume of 0.10 m³. Calculate the new pressure. Use the equation: pressure × volume = constant
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Model answer
\(100\,000 \times 0.30 = p \times 0.10\); \(p = 300\,000\) Pa
Mark scheme
- Correct substitution — 1 mark
- Rearranges — 1 mark
- 300 000 Pa — 1 mark
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Question 4 State 1 mark
State the direction of the force exerted by gas particles on the wall of a container.
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Model answer
At right angles to the wall.
Mark scheme
- At right angles to the wall — 1 mark
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Question 5 Calculate 4 marks
A syringe contains 60 cm³ of air at a pressure of 100 kPa. The plunger is pushed in until the volume is 24 cm³. The temperature is constant. Calculate the new pressure of the air in kPa.
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Model answer
\(100 \times 60 = p \times 24\); \(p = 250\) kPa
Mark scheme
- pV constant — 1 mark
- Correct substitution — 1 mark
- Correct rearrangement — 1 mark
- 250 kPa — 1 mark
Quick check
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Gas pressure is caused by...
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B: particles colliding with the walls
Collisions exert a force on the walls.
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Heating a gas at constant volume makes the pressure...
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C: increase
The particles move faster.
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Halving the volume of a gas at constant temperature makes the pressure...
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D: double
pV = constant.
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The force on a wall from gas pressure is...
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A: at right angles to the wall
It acts perpendicular to the surface.
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The unit of pressure is the...
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B: pascal
Pa = N/m².
Downloads
Free to keep, print and annotate.
- Particle motion and pressure in gases.pptx Built from the lesson script on 30 September 2026. View
- Particle motion and pressure in gases - Completed Notes.docx The full notes for the lesson, to revise from. Built from the lesson script on 30 September 2026. View
- Particle motion and pressure in gases - Exam Questions.docx Built from the lesson script on 30 September 2026. View
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