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Physics · Particle model of matter

Particle motion and pressure in gases

Explain gas pressure using the particle model, describe how temperature and volume affect pressure, and use \(pV = \text{constant}\).

  • 6 key terms
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Teacher resources

The teacher copies: slides with the questions built in, the answers, and anything else attached to this lesson for whoever is teaching it.

Student handouts

The same files the students see, to print or hand out.

Warm-up

Answer each one, then check.

  1. 1

    What is pressure?

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    Force per unit area

  2. 2

    What is the unit of pressure?

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    Pascal (Pa)

  3. 3

    How do gas particles move?

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    Randomly and quickly

  4. 4

    Convert 100 kPa to Pa.

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    100 000 Pa

  5. 5

    Write 3 × 4 = ?

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    12

Learning Objectives

  1. 1Explain how the motion of gas molecules is related to temperature and pressure.
  2. 2Explain qualitatively the relation between temperature and pressure of a gas at constant volume.
  3. 3Explain how changing the volume of a gas at constant temperature changes its pressure.
  4. 4Use \(pV = \text{constant}\).

GAS PRESSURE

Gas molecules are in constant random motion. Their collisions with the container walls cause the pressure, which acts at right angles to the wall.

For a fixed mass of gas at constant temperature, \(pressure \times volume = constant\), \(pV = \text{constant}\). It is given on the equation sheet.

Explaining Pressure

Use this chain of reasoning.

  1. 1 Particles move randomly

    They collide with the walls of the container.

  2. 2 Each collision exerts a tiny force

    At right angles to the wall.

  3. 3 Many collisions

    Together they give a steady force on the wall, and pressure = force ÷ area.

What Affects Gas Pressure

Learn the explanation for each.

  • Temperature up (constant volume)

    Effect on pressure: Increases. Explanation: Particles move faster, so collide harder and more often.

  • Volume down (constant temperature)

    Effect on pressure: Increases. Explanation: Particles are closer together so collide more often with the walls.

  • Volume up (constant temperature)

    Effect on pressure: Decreases. Explanation: Particles collide less often with the walls.

Using pV = constant

A gas at 100 000 Pa occupies 0.30 m³. It is compressed to 0.10 m³ at constant temperature. Calculate the new pressure.

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  1. 1 Write the relationship \(p_1V_1 = p_2V_2\)
  2. 2 Substitute \(100\,000 \times 0.30 = p_2 \times 0.10\)
  3. 3 Rearrange \(p_2 = \dfrac{30\,000}{0.10}\)
  4. 4 Answer \(p_2 = 300\,000\) Pa

Answer300 000 Pa

Heating at Constant Volume

Explain why the pressure in a sealed can increases when it is heated.

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  1. 1 Temperature rises The average kinetic energy of the molecules increases
  2. 2 Faster molecules They hit the walls harder and more often
  3. 3 Result The force on the walls, and so the pressure, increases

AnswerPressure increases because the faster molecules collide with the walls more often and with greater force.

Common Mistakes

Avoid these.

  • Molecules expand

    The molecules do not get bigger: they move faster.

  • Collisions

    Say 'more frequent and harder', not just 'more collisions'.

  • Units

    Pressure in pascals (Pa) and volume in m³.

  • Constant

    pV = constant only for a fixed mass at constant temperature.

Squash the Gas

A syringe holds 60 cm³ of air at 100 kPa. The plunger is pushed until the volume is 20 cm³ at constant temperature. Predict and calculate the new pressure.

1. Use p₁V₁ = p₂V₂.

2. Explain with particles.

A good answer shows: The pressure increases (particles hit the walls more often). p₂ = 100 × 60 ÷ 20 = 300 kPa.

Can I...?

  1. 1Explain gas pressure with particles.
  2. 2Say the force is at right angles to the wall.
  3. 3Explain the effect of temperature.
  4. 4Explain the effect of volume.
  5. 5Use \(pV = \text{constant}\).
  6. 6Give units of pressure.
  7. 7Compress and expand gases.
  8. 8Give clear explanations.

Summary & Exam Focus

  • Gas pressure is caused by collisions with the walls.
  • Higher temperature: faster molecules, more force, more often.
  • Smaller volume at constant temperature: higher pressure.
  • \(pV = \text{constant}\).

Exam focus

Explain, in terms of particles, why the pressure of a gas in a sealed container increases when the gas is heated. (3 marks) (3 marks)

Say faster molecules hit the walls more often and harder.

Key terms

The vocabulary this lesson expects you to use. Each one is linked from the first place it appears above.

Pressure
Force per unit area.
Pascal
The unit of pressure; one newton per square metre.
Random motion
Movement in any direction with no pattern.
Fixed mass
A sealed amount of gas with no particles added or removed.
Compress
Squash into a smaller volume.
Kinetic energy
Energy of movement.

Questions and answers

10 questions set on this lesson, with the mark schemes and model answers open.

1. Exam question Explain 3 marks Easier

A sealed container of gas is heated and the volume is constant. Explain, in terms of the particles, why the pressure of the gas increases.

Mark scheme — 3 marks available

  • Particles move faster or gain kinetic energy — 1 mark
  • Collide with walls more often or harder — 1 mark
  • So pressure increases — 1 mark

Model answer

The particles gain kinetic energy and move faster. They collide with the walls more often and with greater force, so the force on the walls per unit area increases.

2. Exam question Explain 3 marks Easier

The volume of a gas in a syringe is reduced. The temperature is constant. Explain, in terms of the particles, why the pressure increases.

Mark scheme — 3 marks available

  • Volume decreases so the particles are closer — 1 mark
  • More frequent collisions with the walls — 1 mark
  • Pressure increases — 1 mark

Model answer

The particles are closer together, so they collide with the walls more often. The force per unit area increases, so the pressure increases.

3. Exam question Calculate 3 marks Easier

A fixed mass of gas has a pressure of 100 000 Pa and a volume of 0.30 m³. The gas is compressed at constant temperature to a volume of 0.10 m³. Calculate the new pressure. Use the equation: pressure × volume = constant

Mark scheme — 3 marks available

  • Correct substitution — 1 mark
  • Rearranges — 1 mark
  • 300 000 Pa — 1 mark

Model answer

\(100\,000 \times 0.30 = p \times 0.10\); \(p = 300\,000\) Pa

4. Exam question State 1 mark Easier

State the direction of the force exerted by gas particles on the wall of a container.

Mark scheme — 1 mark available

  • At right angles to the wall — 1 mark

Model answer

At right angles to the wall.

5. Exam question Calculate 4 marks Easier

A syringe contains 60 cm³ of air at a pressure of 100 kPa. The plunger is pushed in until the volume is 24 cm³. The temperature is constant. Calculate the new pressure of the air in kPa.

Mark scheme — 4 marks available

  • pV constant — 1 mark
  • Correct substitution — 1 mark
  • Correct rearrangement — 1 mark
  • 250 kPa — 1 mark

Model answer

\(100 \times 60 = p \times 24\); \(p = 250\) kPa

6. Multiple choice 1 mark Easier

Gas pressure is caused by...

  1. A particles melting
  2. B particles colliding with the walls Correct
  3. C gravity only
  4. D the container's colour

Why: Collisions exert a force on the walls.

7. Multiple choice 1 mark Core

Heating a gas at constant volume makes the pressure...

  1. A decrease
  2. B stay the same
  3. C increase Correct
  4. D become zero

Why: The particles move faster.

8. Multiple choice 1 mark Core

Halving the volume of a gas at constant temperature makes the pressure...

  1. A halve
  2. B stay the same
  3. C quadruple
  4. D double Correct

Why: pV = constant.

9. Multiple choice 1 mark Core

The force on a wall from gas pressure is...

  1. A at right angles to the wall Correct
  2. B along the wall
  3. C upwards only
  4. D zero

Why: It acts perpendicular to the surface.

10. Multiple choice 1 mark Stretch

The unit of pressure is the...

  1. A joule
  2. B pascal Correct
  3. C watt
  4. D coulomb

Why: Pa = N/m².