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1.3 Hazard symbols and working safely

Edexcel: the hazard pictograms on chemical containers (flammable, oxidising, corrosive, toxic, harmful, health hazard, environmental hazard, explosive), what they warn about, and how to evaluate risks and choose precautions in practical work.

Edexcel 2 min read

Why hazard symbols are used

Key terms

  • Hazard: something that could cause harm.
  • Risk: the chance that a hazard will cause harm.
  • Precaution: an action taken to reduce a risk.

Hazard symbols on containers of chemicals:

  • show the dangers associated with the contents
  • tell people about safe-working precautions when they use the chemicals in the lab or in industry.

They are recognised worldwide, so people can understand them whatever language they speak.

Eight hazard pictograms in red diamonds: flammable, oxidising, corrosive, toxic, harmful or irritant, health hazard, environmental hazard and explosive
Eight hazard pictograms in red diamonds: flammable, oxidising, corrosive, toxic, harmful or irritant, health hazard, environmental hazard and explosive
Hazard symbols and precautions
SymbolMeaningExamplePrecaution
FlammableCatches fire easilyEthanolKeep away from flames
OxidisingProvides oxygen, making other things burn more fiercelyHydrogen peroxideKeep away from flammable materials
CorrosiveAttacks and destroys living tissue, such as skin and eyesConcentrated sulfuric acid, sodium hydroxideWear gloves and eye protection
ToxicCan cause death if swallowed, breathed in or absorbed through skinChlorine, mercuryUse in a fume cupboard; wear gloves
Harmful / irritantCan cause irritation, such as reddening or blistering of skinDilute acids, copper sulfateAvoid contact with skin; wear eye protection
Health hazardCan cause long-term health effects, such as cancerSome solventsAvoid breathing in; use in a fume cupboard
Environmental hazardHarmful to living things in the environmentMercury compoundsDispose of safely, not down the sink

Evaluating risks in a practical

For any practical, think about:

  1. the hazards: which chemicals and equipment could cause harm (hot apparatus, glass, chemicals)
  2. the risk: how likely harm is, and how serious it would be
  3. the precautions: for example wearing eye protection, using lower concentrations, heating with a water bath instead of a flame, working in a fume cupboard, keeping flammable liquids away from flames.

Test yourself on this lesson

5 exam questions · 8 marks · with mark schemes and model answers

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