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1.12 Group 0: the noble gases

Why the noble gases are unreactive and exist as single atoms, how their boiling points change down the group, how to predict properties from the trend, and how their uses depend on their properties.

AQA Edexcel OCR 2 min read

The noble gases

Key terms

  • Noble gases: the elements in Group 0 (helium, neon, argon, krypton, xenon and radon).
  • Inert: very unreactive; does not take part in chemical reactions easily.
  • Monatomic: existing as single atoms rather than as molecules.
  • Their atoms have a full outer shell of electrons: helium has 2, and the others have 8.
  • This is a stable arrangement, so they do not easily lose, gain or share electrons. They are unreactive (inert).
  • Because they do not bond, they exist as single atoms (they are monatomic), not as molecules like O2.
  • They are all colourless gases at room temperature and are non-flammable.
Shell diagrams of helium (2), neon (2.8) and argon (2.8.8) with full outer shells, and a bar chart of boiling points rising from −269 °C for helium to −62 °C for radon
Shell diagrams of helium (2), neon (2.8) and argon (2.8.8) with full outer shells, and a bar chart of boiling points rising from −269 °C for helium to −62 °C for radon
  • Boiling points increase down the group, as the relative atomic mass increases. The atoms are larger with more electrons, so the forces between atoms are stronger and more energy is needed to separate them.
  • Density increases down the group.
Data for the noble gases
ElementRelative atomic massBoiling point in °C
Helium4−269
Neon20−246
Argon40−186
Krypton84−153
Xenon131−108
Radon222−62

Uses depend on properties

  • Helium in balloons and airships: it is much less dense than air and, unlike hydrogen, it is non-flammable.
  • Argon in filament lamps: it is inert, so the very hot metal filament does not react with it (in air, the filament would burn in oxygen).
  • Argon as a shield gas in welding: it stops the hot metal reacting with oxygen.
  • Neon in advertising signs: it glows when electricity passes through it and does not react.

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